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US 10,099,975 B2Granted
Alkynyl-tolanes, liquid-crystal mixtures containing them and components for high-frequency technology
AssigneeMerck Patent GmbH
InventorsChristian Jasper, Constanze Brocke, Detlef Pauluth, Volker Reiffenrath, Atsutaka Manabe
Life of this patent
Estimating the term…
Abstract
Compounds of formula I their use in liquid-crystalline media, for example, for the phase shifting of microwaves for tunable phased-array antennae, and their use for high-frequency components, in particular antennae, especially for the gigahertz range.
Claims22
A compound of formula I
- in which
- where in the 1,4-phenylene groups, one C—H group or two C—H groups are optionally replaced by N,
- Y denotes S or O,
- L0 on each occurrence, independently of one another, denotes H, Br, Cl, F, —CN, —NCS, —SCN, SF5, C1-C10 alkyl, C1-C10 alkoxy, C3-C6 cycloalkyl or a mono- or polyfluorinated C1-C10 alkyl or alkoxy group,
- R01 and R02 each, independently of one another, denote a halogenated or unsubstituted alkyl radical having 1 to 15 C atoms, in which one or more CH2 groups are optionally replaced, independently of one another, by —C≡C—, —CH═CH—, —CF═CF—, —CF═CH—, —CH═CF—, —(CO)O—, —O(CO)—, —(CO)—, —O— or —S— in such a way that O or S atoms are not linked directly to one another, and R01 also denotes ethynyl, and
- R03 and R04 each, independently of one another, denote a halogenated or unsubstituted alkyl radical having 1 to 6 C atoms, in which one or more CH2 groups are optionally replaced, independently of one another, by —C≡C—, —CH═CH—, —CF═CF—, —CF═CH—, —CH═CF—, —(CO)O—, —O(CO)—, —(CO)—, —O— or —S— in such a way that O or S atoms are not linked directly to one another.
3 more elements
A compound of formula I
- in which
- where in the 1,4-phenylene groups, one C—H group or two C—H groups are replaced by N, which one C—H group or two C—H groups are present as a result of L0 being H on the carbon atom of said one C—H group or two C—H groups,
- where in the 1,4-phenylene groups, one C—H group or two C—H groups are optionally replaced by N,
- L0 on each occurrence, independently of one another, denotes H, Br, Cl, F, —CN, —NCS, —SCN, SF5, C1-C10 alkyl, C1-C10 alkoxy, C3-C6 cycloalkyl or a mono- or polyfluorinated C1-C10 alkyl or alkoxy group,
- R01 and R02 each, independently of one another, denote a halogenated or unsubstituted alkyl radical having 1 to 15 C atoms, in which one or more CH2 groups are optionally replaced, independently of one another, by —C≡C—, —CH═CH—, —CF═CF—, —CF═CH—, —CH═CF—, —(CO)O—, —O(CO)—, —(CO)—, —O— or —S— in such a way that O or S atoms are not linked directly to one another, and R01 also denotes ethynyl, and
- R03 and R04 each, independently of one another, denote a halogenated or unsubstituted alkyl radical having 1 to 6 C atoms, in which one or more CH2 groups are optionally replaced, independently of one another, by —C≡C—, —CH═CH—, —CF═CF—, —CF═CH—, —CH═CF—, —(CO)O—, —O(CO)—, —(CO)—, —O— or —S— in such a way that O or S atoms are not linked directly to one another.
3 more elements
Dependencies are inferred from the claim text.