Method of producing double-doped scintillation crystal
AssigneeNational Sun Yat-Sen University
InventorMing-Chi Chou
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Abstract
A method of producing a double-doped scintillation crystal is provided. Czochralski method is used to grow a double-doped single crystal boule. The double-doped single crystal boule is a single crystal boule of rare-earth silicate double-doped with cerium (Ce) and calcium (Ca) or magnesium (Mg). The double-doped single crystal boule is subjected to a thermal annealing process in a furnace. A yield of pixel samples of the double-doped scintillation crystal is improved after a processing process, and the present invention achieves low producing cost, high yield, less crystal fragmentations, high luminescence intensity and short decaying time.
Claims4
A method of producing a double-doped scintillation crystal, comprising steps of:
- (A) growing a double-doped single crystal boule by Czochralski method, wherein said double-doped single crystal boule has a diameter of 70 mm and a length of 200 mm, said double-doped single crystal boule is a single crystal boule having general formula (I) or (II), and tetravalent cerium (Ce4+) become trivalent cerium (Ce3+) by charge compensation,
- Cax+Cey:Lu2−x−y−zYzSiO5 (I)
- Mgx+Cey:Lu2−x−y−zYzSiO5 (II)
- in the general formula (I) and (II), x is 0.003, y is more than 0.001 to less than 0.1, and z is equal to or greater than 0.05 to less than 1.898;
- and
- (B) performing a thermal annealing process by placing the double-doped single crystal boule in a furnace, so as to form said double-doped scintillation crystal boule, wherein said thermal annealing process comprises:
- a heating step, wherein the double-doped single crystal boule is heated from a room temperature to a temperature of 1400° C. ˜1600° C. in 480 minutes (mins)˜600 mins;
- a temperature-sustaining step, wherein said temperature is maintained at 1400° C. ˜1600° C. for 50 hours (hrs)˜200 hrs and
- a cooling step, wherein said double-doped single crystal boule is cooled down from 1400° C.˜1600° C. to a room temperature in 480 mins ˜720 mins.
Dependencies are inferred from the claim text.