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US 10,093,781 B2Granted
Foamed styrenic polymers containing a brominated styrene-butadiene copolymer and having enhanced cell size homogeneity
AssigneeDow Global Technologies LLC
InventorsKenji Matsue, Naganori Nishioka, Yoshihiro Shirakawa, Lawrence S. Hood, Shari L. Kram, Stephane Costeux, Mark A. Barger
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Abstract
Extruded polymer foams are made from a polymer composition that includes an unbrominated styrenic polymer, a brominated vinyl aromatic/butadiene flame retardant, and an unbrominated vinyl aromatic/butadiene polymer. The unbrominated vinyl aromatic/butadiene polymer improves the cell homogeneity.
Claims12
A monolithic foamed polymer composition having a polymeric phase which contains gas-filled cells, wherein the polymer phase comprises:
- (a) one or more thermoplastic, non-brominated styrenic polymers containing no more than 1% polymerized diene monomers,
- (b) a thermoplastic brominated vinyl aromatic/butadiene copolymer having a molecular weight of at least 1000 g/mol in an amount sufficient to provide 0.25 to 5% by weight bromine based on the combined weights of components (a), (b) and (c), and
- (c) from 0.1 to 5 parts by weight, per part by weight of component (b) of at least one thermoplastic unbrominated vinyl aromatic/butadiene block copolymer selected from the group consisting of a thermoplastic unbrominated styrene-butadiene-styrene triblock copolymer containing a central poly(butadiene) block of 30,000 to 100,000 g/mol and terminal polystyrene blocks each having a molecular weight of 20,000 to 100,000 g/mol and a thermoplastic unbrominated styrene-butadiene diblock copolymer in which the polystyrene block has a molecular weight of 30,000 to 75,000 g/mol and the poly(butadiene) block has a molecular weight of 40,000 to 100,000 g/mol.
Dependencies are inferred from the claim text.