Producing high comonomer content propylene-based polymers
AssigneeW. R. Grace & Co.-Conn.
InventorsPing Cai, Matthew J. Fedec, Jeffrey D. Goad, Jan W. Van Egmond, Chai-Jing Chou
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AssigneeW. R. Grace & Co.-Conn.
InventorsPing Cai, Matthew J. Fedec, Jeffrey D. Goad, Jan W. Van Egmond, Chai-Jing Chou
Estimating the term…
A gas-phase process for making a propylene-based polymer in a fluidized-bed reactor, the reactor containing a fluidized bed including polymer product particles and a catalyst, the process having a set of quantitative criteria for maximum monomer partial pressure, maximum reactor temperature, and comonomer content(s) in the propylene-based polymer. The propylene-based polymer may be EBPT or BPRCP. The catalyst may include a catalyst/donor system comprising (1) a supported Ziegler-Natta pro-catalyst, (2) a co-catalyst, and (3) a mixed external electron donor system including (a) an activity limiting agent including at least one carboxylate ester functional group, and (b) a selectivity control agent.
A process of producing a propylene-based polymer, the process comprising contacting, under copolymerization conditions, (A) propylene, butene and optionally ethylene, in a fluidized-bed reactor, the reactor containing (B) a fluidized bed comprising propylene-based polymer product particles and a catalyst, the propylene-based polymer having a seal initiation temperature (SIT) of 75° C. to 110° C., the process conducted under copolymerization conditions comprising a reactor temperature that is 20° C. to 40° C. less than the SIT of the propylene-based polymer;
A process of producing a propylene-based polymer in a fluidized-bed reactor comprising propylene-based polymer product particles and a catalyst, the propylene-based polymer having a seal initiation temperature (SIT) of 75° C. to 110° C., the process conducted under copolymerization conditions comprising a reactor temperature and a propylene partial pressure in a range of 80% to 120% of the maximum partial pressure, PPC3_max, as determined by the following equation:
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