Solid electrolyte
AssigneeIdemitsu Kosan Co., Ltd.
InventorsTakayoshi Kambara, Hiroyuki Higuchi, Hiroyuki Tamura, Masaru Nakagawa, Tadanori Junke
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Abstract
A solid electrolyte glass at least including: at least one alkali metal element; a phosphorus (P) element; a sulfur (S) element; and one or more halogen elements selected from I, Cl, Br and F; wherein the solid electrolyte glass has two exothermic peaks that are separated from each other in a temperature range of 150° C. to 350° C. as determined by differential scanning calorimetry (in a dry nitrogen atmosphere at a temperature-elevating speed of 10° C./min from 20 to 600° C.).
Claims11
A solid electrolyte glass ceramic represented by the formula (1):
- LaMbPcSdXe (1)
- wherein:
- L is an alkali metal;
- M is one or more elements selected from the group consisting of B, Al, Si, Ge, As, Se, Sn, Sb, Te, Pb and Bi;
- and
- X includes Br and optionally further includes at least one halogen element selected from the group consisting of I, Cl, and F;
- and
- a to e independently satisfy:
- 0<a≤12,
- 0≤b≤0.2,
- c=1,
- 0<d≤9, and
- 0<e≤9,
- wherein the solid electrolyte glass ceramic has one exothermic peak in a temperature range of 150° C. to 350° C. as determined by differential scanning calorimetric measurement (in a dry nitrogen atmosphere at a temperature-elevating speed of 10° C./min from 20 to 600° C.), and
- the solid electrolyte glass ceramic is obtained by subjecting a solid electrolyte glass which has two exothermic peaks that are separated from each other in a temperature range of 150° C. to 350° C. as determined by differential scanning calorimetric measurement (in a dry nitrogen atmosphere at a temperature-elevating speed of 10° C./min from 20 to 600° C.) to a heat treatment at a temperature between the two exothermic peaks.
Dependencies are inferred from the claim text.