Absorbent articles comprising organopolysiloxane conditioning polymers

A disposable absorbent article comprising a topsheet, a backsheet, and an absorbent core disposed between said topsheet and said backsheet, wherein said topsheet comprises a nonwoven fabric coated with a blocky cationic organopolysiloxane having the formula:

• MwDxTyQz
• wherein:
• M=[SiR1R2R3 O1/2], [SiR1R2G1O1/2], [SiR1G1G2O1/2 ], [SiG1G2G3O1/2 ], or combinations thereof;
• D=[SiR1R2O2/2], [SiR1G1O2/2], [SiG1G2O2/2] or combinations thereof;
• T=[SiR1O3/2], [SiG1O3/2] or combinations thereof;
• Q=[SiO4/2];
• w=is an integer from 1 to (2+y+2z);
• x=is an integer from 5 to 15,000;
• y=is an integer from 0 to 98;
• z=is an integer from 0 to 98;
• R1, R2 and R3 are each independently selected from the group consisting of H, OH, C1-C32 alkyl, C1-C32 substituted alkyl, C5-C32 aryl, C5-C32 substituted aryl, C6-C32 alkylaryl, C6-C32 substituted alkylaryl, C1-C32 alkoxy, C1-C32 substituted alkoxy, C1-C32 alkylamino, and C1-C32 substituted alkylamino;
• at least one of M, D, or T incorporates at least one moiety G1, G2 or G3;
• and
• G1, G2, and G3 are identical or different moieties, each of which has the formula:
• wherein:
• X comprises a divalent radical selected from the group consisting of C1-C32 alkylene, C1-C32 substituted alkylene, C5-C32 arylene, C5-C32 substituted arylene, C6-C32 arylalkylene, C6-C32 substituted arylalkylene, C1-C32 alkoxy, C1-C32 substituted alkoxy, C1-C32 alkyleneamino, C1-C32 substituted alkyleneamino, ring-opened epoxide, and ring-opened glycidyl, with the proviso that if X does not comprise a repeating alkylene oxide moiety then X can further comprise a heteroatom selected from the group consisting of P, N and O;
• each R4 comprises identical or different monovalent radicals independently selected from the group consisting of H, C1-C32 alkyl, C1-C32 substituted alkyl, C5-C32 aryl, C5-C32 substituted aryl, C6-C32 alkylaryl, and C6-C32 substituted alkylaryl;
• E comprises a divalent radical selected from the group consisting of C1-C32 alkylene, C1-C32 substituted alkylene, C5-C32 arylene, C5-C32 substituted arylene, C6-C32 arylalkylene, C6-C32 substituted arylalkylene, C1-C32 alkoxy, C1-C32 substituted alkoxy, C1-C32 alkyleneamino, C1-C32 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E does not comprise a repeating alkylene oxide moiety then E can further comprise a heteroatom selected from the group consisting of P, N, and O;
• E′ comprises a divalent radical selected from the group consisting of C1-C32 alkylene, C1-C32 substituted alkylene, C5-C32 arylene, C5-C32 substituted arylene, C6-C32 arylalkylene, C6-C32 substituted arylalkylene, C1-C32 alkoxy, C1-C32 substituted alkoxy, C1-C32 alkyleneamino, C1-C32 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E′ does not comprise a repeating alkylene oxide moiety then E′ can further comprise a heteroatom selected from the group consisting of P, N, and O;
• p is an integer independently selected from 1 to 50;
• n is an integer independently selected from 1 or 2;
• when at least one of G1, G2, or G3 is positively charged, A−t is a suitable charge balancing anion or anions such that the total charge, k, of the charge-balancing anion or anions is equal to and opposite from the net charge on the moiety G1, G2 or G3;
• where t is an integer independently selected from 1, 2, or 3;
• and wherein k ≤p*2/t+1, for each moiety G.