US 10,072,171 B2Granted

Olefin-based paint containing propylene/α-olefin copolymer

AssigneeMitsui Chemicals, Inc.

InventorsKuniaki Kawabe, Hirotaka Kanaya, Masakazu Tanaka, Toshiyuki Ito

Life of this patent

Estimating the term…

Loading patent…

Abstract

The present invention relates to an olefin-based paint. The purpose of the present invention is to provide a paint with excellent organic solvent solubility or dispersibility, low paint viscosity, minimal coating irregularities even at high concentrations, excellent handling and storage stability, and excellent blocking resistance and coated film stability. In order to meet this purpose, an olefin-based paint is used that is characterized by containing a solution or dispersion obtained by dissolving or dispersing 0.1-55 parts by mass of a propylene-α-olefin copolymer (A) for 100 parts by mass of an organic solvent. The copolymer (A) is characterized by containing 60-90 mol % of propylene-derived constituent units (a) having a weight-average molecular weight (Mw), measured by GPC, in the range of 3,000 to 40,000, and 10-40 mol % of α-olefin-derived constituent units (b) having 4 or more carbon atoms [wherein (a)+(b)=100 mol %].

Claims10

Dependent claims

An olefin-based coating material comprising a solution or dispersion in which 0.1 to 55 parts by mass of a propylene-α-olefin copolymer (A) which satisfies the following requirements (i) to (iii) is dissolved or dispersed in 100 parts by mass of an organic solvent:

(i) a weight-average molecular weight (Mw) measured by gel permeation chromatography (GPC) is in the range of 3,000 to 40,000;
(ii) the propylene-α-olefin copolymer (A) contains propylene-derived structural units (a) in the range of 60 to 90 mol %, and structural units (b) derived from α-olefin having not less than 4 carbon atoms in the range of 10 to 40 mol % (wherein (a)+(b)=100 mol %);
and
(iii) the number of vinylidene groups per 1,000 carbon atoms is 0.5 to 5 as measured by 1H-NMR;
wherein the propylene-α-olefin copolymer (A) is obtained through thermal decomposition of a propylene-α-olefin copolymer (A-1) which satisfies the following requirements (a) to (c):
(a) a weight-average molecular weight (Mw), measured by GPC is in the range of 50,000 to 1,000,000;
(b) a melting point (Tm) obtained from DSC is in the range of 60 to 120° C.;
and
(c) a half-width of the melting peak obtained from DSC is in the range of 1 to 20° C.

6 more elements

Dependencies are inferred from the claim text.