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US 10,065,905 B2Granted
Reactivating propane dehydrogenation catalyst
AssigneeDow Global Technologies LLC
InventorsMatthew Pretz, Lin Luo, Susan Domke, Howard W. Clark, Richard A. Pierce, Andrzej M. Malek, Mark W. Stewart, Brien A. Stears, Albert E. Schweizer, Jr., Guido Capone, Duncan P. Coffey, Isa K. Mbaraka
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Abstract
Increase propane dehydrogenation activity of a partially deactivated dehydrogenation catalyst by heating the partially deactivated catalyst to a temperature of at least 660° C., conditioning the heated catalyst in an oxygen-containing atmosphere and, optionally, stripping molecular oxygen from the conditioned catalyst.
Claims12
A process for dehydrogenating an alkane, the process comprising:
- a. placing an alkane in operative contact with a heated alkane dehydrogenation catalyst in a reactor, the alkane dehydrogenation catalyst comprising a Group VIII noble metal and a Group IIIA metal;
- b. removing from the reactor a partially deactivated catalyst, wherein at least a portion of the partially deactivated catalyst has coke deposited thereon;
- c. rejuvenating at least a portion of the partially deactivated catalyst, yielding a rejuvenated dehydrogenation catalyst, by:
- (1) heating at least a portion of the partially deactivated catalyst in a regenerator to a temperature of at least 660 degrees Celsius using heat at least partially generated by combusting a fuel source, wherein the fuel source is not the coke, said heating yielding a heated, further deactivated dehydrogenation catalyst which has an alkane dehydrogenation activity that is less than that of the partially deactivated catalyst;
- and
- (2) subjecting at least a portion of the heated, further deactivated catalyst to a conditioning step which comprises maintaining at least a portion of the heated, further deactivated dehydrogenation catalyst at a temperature of at least 660 degrees Celsius while exposing at least a portion of the heated, further deactivated dehydrogenation catalyst to a flow of an oxygen-containing gas for a period of time greater than two minutes to yield an oxygen-containing reactivated dehydrogenation catalyst that has an activity for dehydrogenating alkane that is greater than that of either the partially deactivated catalyst or the heated, further deactivated catalyst.
3 more elements
Dependencies are inferred from the claim text.