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US 10,059,724 B2Granted
Pyridine complex of zirconium, catalytic system comprising said pyridine complex of zirconium and process of (co)polymerization of conjugated dienes
AssigneeVersalis S.P.A.
InventorsGuido Pampaloni, Giovanni Ricci, Anna Sommazzi, Francesco Masi, Giuseppe Leone
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Abstract
Pyridine complex of zirconium having general formula (I): Said pyridine complex of zirconium having general formula (I) may advantageously be used in a catalytic system for the (co)polymerization of conjugated dienes.
Claims12
Pyridine complex of zirconium having general formula (I):
- in which:
- R1 and R2, identical or different, represent a hydrogen atom;
- or are selected from linear or branched, optionally halogenated C1-C20, alkyl groups, optionally substituted cycloalkyl groups, or optionally substituted aryl groups;
- R3, R4, R5 and R6, identical or different, represent a hydrogen atom;
- or are selected from linear or branched, optionally halogenated C1-C20, alkyl groups, optionally substituted cycloalkyl groups, optionally substituted aryl groups, nitro groups, hydroxyl groups, or amino groups;
- X1, X2 and X3, identical or different, represent a halogen atom;
- or are selected from linear or branched C1-C20, alkyl groups, —OCOR7 groups or —OR7 groups in which R7 is selected from linear or branched C1-C20, alkyl groups;
- or one of X1, X2 and X3 represents a group having general formula (II):
- in which R1, R2, R3, R4, R5 and R6, have the same meanings described above.
6 more elements
Dependencies are inferred from the claim text.