Aqueous dispersion of fluorine-containing copolymer
AssigneeUnimatec Co., Ltd.
InventorYoshiyama Kaneumi
Life of this patent
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Abstract
An aqueous dispersion of a fluorine-containing copolymer comprising, as copolymerization units, (A) a (meth)acrylate represented by [CH2═CHRCOO(NH)rR1NR2R3R4]+Y−, (B) a perfluoroalkylalkyl(meth)acrylate represented by CmF2m+1CpH2p(NR′SO2)qOCOCR═CH2 or a polyfluoroalkylalkyl(meth)acrylate thereof, or a polyfluoroalkyl(meth)acrylate represented by CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2, (C) benzyl(meth)acrylate, (D) a fluorine-free polymerizable monomer other than components (A) and (C), and (E) a crosslinkable group-containing polymerizable monomer. The aqueous dispersion can improve the dispersion stability of an aqueous dispersion of a water- and oil-repellent when used as a water- and oil-repellent comprising the fluorine-containing copolymer as an active component.
Claims8
An aqueous dispersion of a fluorine-containing copolymer comprising, as copolymerization units,
- (A) a (meth)acrylate represented by the general formula:
- [CH2═CHRCOO(NH)rR1NR2R3R4]+Y− [I]
- wherein R is a hydrogen atom or a methyl group;
- R1 is a linear, branched, or alicyclic alkylene group having 1 to 30 carbon atoms or a phenylene group;
- R2, R3, and R4 are the same or different and each is a linear, branched, or alicyclic alkyl group having 1 to 30 carbon atoms or an aralkyl group;
- r is 0 or 1;
- and Y− is an anionic group;
- (B)
- a perfluoroalkylalkyl(meth)acrylate represented by the general formula:
- CmF2m+1CpH2p(NR′SO2)qOCOCR═CH2 [IIa]
- wherein R is a hydrogen atom or a methyl group, R′ is an alkyl group having 1 to 5 carbon atoms, m is an integer of 4 to 14, p is an integer of 1 to 4, and q is 0 or 1;
- a polyfluoroalkylalkyl(meth)acrylate which is prepared by replacing some of the fluorine atoms in the perfluoroalkyl group in the above perfluoroalkylalkyl(meth)acrylate with hydrogen atoms;
- or
- a polyfluoroalkyl(meth)acrylate represented by the general formula:
- CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2 [IIb]
- wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3;
- (C) benzyl(meth)acrylate;
- (D) a fluorine-free polymerizable monomer other than components (A) and (C);
- and
- (E) a crosslinkable group-containing polymerizable monomer,
- wherein 0.1 to 1.0 wt. % of component (A), 10 to 80 wt. % of component (B), 5 to 80 wt. % of component (C), 1 to 30 wt. % of component (D), and 0.3 to 30 wt. % of component (E), each in the fluorine-containing copolymer, are copolymerized using a water-soluble polymerization initiator.
A fluorine-containing copolymer comprising, as copolymerization units,
- (A) a (meth)acrylate represented by the general formula:
- [CH2═CHRCOO(NH)rR1NR2R3R4]+Y− [I]
- wherein R is a hydrogen atom or a methyl group;
- R1 is a linear, branched, or alicyclic alkylene group having 1 to 30 carbon atoms or a phenylene group;
- R2, R3, and R4 are the same or different and each is a linear, branched, or alicyclic alkyl group having 1 to 30 carbon atoms or an aralkyl group;
- r is 0 or 1;
- and Y− is an anionic group;
- (B)
- a perfluoroalkylalkyl(meth)acrylate represented by the general formula:
- CmF2m+1CpH2p(NR′SO2)qOCOCR═CH2 [IIa]
- wherein R is a hydrogen atom or a methyl group, R′ is an alkyl group having 1 to 5 carbon atoms, m is an integer of 4 to 14, p is an integer of 1 to 4, and q is 0 or 1;
- a polyfluoroalkylalkyl(meth)acrylate which is prepared by replacing some of the fluorine atoms in the perfluoroalkyl group in the perfluoroalkylalkyl(meth)acrylate with hydrogen atoms;
- or
- a polyfluoroalkyl(meth)acrylate represented by the general formula:
- CnF2n+1(CH2CF2)e(CF2CF2)b(CH2CH2)cOCOCR═CH2 [IIb]
- wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3;
- (C) benzyl(meth)acrylate;
- (D) a fluorine-free polymerizable monomer other than components (A) and (C);
- and
- (E) a crosslinkable group-containing polymerizable monomer, wherein 0.1 to 1.0 wt. % of component (A), 10 to 80 wt. % of component (B), 5 to 80 wt. % of component (C), 1 to 30 wt. % of component (D), and 0.3 to 30 wt. % of component (E) are copolymerized using a water-soluble polymerization initiator.
Dependencies are inferred from the claim text.