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US 10,000,632 B2Granted
Rubbers with tunable levels of metal containing anti-agglomerants
AssigneeArlanxeo Singapore Pte. Ltd.
InventorsDavid Thompson, Clinton Lund
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Abstract
The invention relates to an efficient process for the preparation and isolation of rubber particles formed in aqueous media having a tunable level of metal containing anti-agglomerants and rubber particles obtained thereby. The invention further relates to copolymer products comprising the same or derived therefrom.
Claims15
A process for the preparation of an aqueous slurry comprising a plurality of copolymer particles suspended therein, the process comprising:
- contacting monomers comprising at least one isoolefin monomer and at least one multiolefin monomer in an organic diluent with an initiator system to polymerize the monomers to form copolymers in a medium comprising the copolymers, the organic diluent and optionally residual monomers;
- contacting the copolymer medium with an aqueous medium comprising at least one lower critical solution temperature compound having a cloud point of 0 to 100° C.;
- and
- removing at least partially the organic diluent and to the extent present in the medium removing at least partially the residual monomers to obtain an aqueous slurry comprising copolymer particles.
1 more element
Dependencies are inferred from the claim text.